In this article, new Gibbs free energy of mixing is derived when there are specific interactions between solvent-solute molecules and between solute-solute molecules in binary solutions. It is asssumed that a probability of specific interactions satisfies a binomial distribution. Using this Gibbs free energy of mixing, we investigate possible types of partial miscibilities and show that Ω-shaped temperature-composition phase diagrams can exist. We calculate Ω-shaped temperature-composition phase diagram of water-2-butanol system and compare that with result calculated by the method of Hino<sup>5</sup> et al. and the experimental data.
@article{ JCGMDC_2016_v60n2_111}
,title={Partial Miscibilities in Binary Solutions with Two Kinds of Specific Interactions}
,volume={2}
, url={http://dx.doi.org/10.5012/jkcs.2016.60.2.111}, DOI={10.5012/jkcs.2016.60.2.111}
, number= {2}
, journal={Journal of the Korean Chemical Society}
, publisher={Korean Chemical Society}
, author={Hae-Young, Jung}
, year={2016}
, month={Apr}
TY - JOUR
T2 - Journal of the Korean Chemical Society
AU - Hae-Young, Jung
SN - 1017-2548
TI - Partial Miscibilities in Binary Solutions with Two Kinds of Specific Interactions
VL - 60
PB - Korean Chemical Society
DO - 10.5012/jkcs.2016.60.2.111
PY - 2016
UR - http://dx.doi.org/10.5012/jkcs.2016.60.2.111
ER -
Hae-Young, J.
( 2016).
Partial Miscibilities in Binary Solutions with Two Kinds of Specific Interactions.
Journal of the Korean Chemical Society,
60
(2)
Korean Chemical Society.
doi:10.5012/jkcs.2016.60.2.111
&
Hae-Young, J
2016,
Partial Miscibilities in Binary Solutions with Two Kinds of Specific Interactions,
Journal of the Korean Chemical Society,
vol. 2,
no. 2,
Retrieved from http://dx.doi.org/10.5012/jkcs.2016.60.2.111
[1]
and
J Hae-Young
,
“Partial Miscibilities in Binary Solutions with Two Kinds of Specific Interactions”,
Journal of the Korean Chemical Society,
vol. 2,
no. 2,
Apr
2016.
Hae-Young, Jung
and
.
“Partial Miscibilities in Binary Solutions with Two Kinds of Specific Interactions”
Journal of the Korean Chemical Society,
2.
2
2016:
Hae-Young, J
Partial Miscibilities in Binary Solutions with Two Kinds of Specific Interactions.
Journal of the Korean Chemical Society
[Internet].
2016.
Apr ;
2
(2)
Available from http://dx.doi.org/10.5012/jkcs.2016.60.2.111
and
Hae-Young, Jung
.
“Partial Miscibilities in Binary Solutions with Two Kinds of Specific Interactions.”
Journal of the Korean Chemical Society
2
no.2
()
Apr,
2016):
http://dx.doi.org/10.5012/jkcs.2016.60.2.111