In order to find out the microscopic environmental information on the nonionic reverse micelle of Triton X-100/n-hexanol/water in cyclohexane, an absorption and fluorescence spectroscopic study has been conducted using a methylene blue(MB). The information on the microscopic states of water in the polar core of the reverse micelle has been found by investigating complex formation and solvatochromic behavior between MB and Triton X-100. As a result, it was found that there exist three states in the polar core of the reverse micelle. The measured values of $W(=[H_2O]/[Surf])$ for the three states of water are 0.71, 4.98, and 7.26, and the corresponding lifetimes of MB are $15.45 ns{\pm}0.56$, $12.27 ns{\pm}0.79$, and $8.28 ns{\pm}0.82$, respectively.
@article{ JCGMDC_2003_v47n4_309}
,title={Spectroscopic Study on Three States of Water in the Reverse Micelle Using Methylene Blue as a Probe}
,volume={4}
, url={http://dx.doi.org/10.5012/jkcs.2003.47.4.309}, DOI={10.5012/jkcs.2003.47.4.309}
, number= {4}
, journal={Journal of the Korean Chemical Society}
, publisher={Korean Chemical Society}
, author={Bum Young, Park
and
Kab Sang, Jung
and
Soo-Chang, Yu
and
Ho Seob, Choi}
, year={2003}
, month={Aug}
TY - JOUR
T2 - Journal of the Korean Chemical Society
AU - Bum Young, Park
AU - Kab Sang, Jung
AU - Soo-Chang, Yu
AU - Ho Seob, Choi
SN - 1017-2548
TI - Spectroscopic Study on Three States of Water in the Reverse Micelle Using Methylene Blue as a Probe
VL - 47
PB - Korean Chemical Society
DO - 10.5012/jkcs.2003.47.4.309
PY - 2003
UR - http://dx.doi.org/10.5012/jkcs.2003.47.4.309
ER -
Bum Young, P.
,
Kab Sang, J.
,
Soo-Chang, Y.
,
&
Ho Seob, C.
( 2003).
Spectroscopic Study on Three States of Water in the Reverse Micelle Using Methylene Blue as a Probe.
Journal of the Korean Chemical Society,
47
(4)
Korean Chemical Society.
doi:10.5012/jkcs.2003.47.4.309
Bum Young, P
,
Kab Sang, J
,
Soo-Chang, Y
,
&
Ho Seob, C
2003,
Spectroscopic Study on Three States of Water in the Reverse Micelle Using Methylene Blue as a Probe,
Journal of the Korean Chemical Society,
vol. 4,
no. 4,
Retrieved from http://dx.doi.org/10.5012/jkcs.2003.47.4.309
[1]
P Bum Young
,
J Kab Sang
,
Y Soo-Chang
,
and
C Ho Seob
,
“Spectroscopic Study on Three States of Water in the Reverse Micelle Using Methylene Blue as a Probe”,
Journal of the Korean Chemical Society,
vol. 4,
no. 4,
Aug
2003.
Bum Young, Park
Kab Sang, Jung
Soo-Chang, Yu
et al.
“Spectroscopic Study on Three States of Water in the Reverse Micelle Using Methylene Blue as a Probe”
Journal of the Korean Chemical Society,
4.
4
2003:
Bum Young, P
,
Kab Sang, J
,
Soo-Chang, Y
,
Ho Seob, C
Spectroscopic Study on Three States of Water in the Reverse Micelle Using Methylene Blue as a Probe.
Journal of the Korean Chemical Society
[Internet].
2003.
Aug ;
4
(4)
Available from http://dx.doi.org/10.5012/jkcs.2003.47.4.309
Bum Young, Park
,
Kab Sang, Jung
,
Soo-Chang, Yu
,
and
Ho Seob, Choi
,
“Spectroscopic Study on Three States of Water in the Reverse Micelle Using Methylene Blue as a Probe.”
Journal of the Korean Chemical Society
4
no.4
()
Aug,
2003):
http://dx.doi.org/10.5012/jkcs.2003.47.4.309