The reaction of $[Cu(L)]Cl_2{\cdot}H_2O(L=3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,0^{1.18},0^{7.12}]docosane)$ with 2,5-pyridinedicarboxylate(pdc) led to the formation of $[Cu(L)(H_2O)](pdc){\cdot}6H_2O(1)$. The structure was characterized by X-ray crystallography and spectroscopic method. The coordination geometry around the copper atom is a distorted square-pyramid with four secondary amines of the macrocycle occupying the basal sites and a water molecule at the axial position. Intermolecular hydrogen bonds in 1 form a three-dimensional molecular network.
@article{ JCGMDC_2003_v47n2_104}
,title={Self-Assembly of Three-Dimensional Copper(II) Macrocyclic Complex with 2,5-Pyridinedicarboxylate Linked by Hydrogen Bond}
,volume={2}
, url={http://dx.doi.org/10.5012/jkcs.2003.47.2.104}, DOI={10.5012/jkcs.2003.47.2.104}
, number= {2}
, journal={Journal of the Korean Chemical Society}
, publisher={Korean Chemical Society}
, author={Ki-Young, Choi
and
Haiil, Ryu
and
Yong-Son, Kim}
, year={2003}
, month={Apr}
TY - JOUR
T2 - Journal of the Korean Chemical Society
AU - Ki-Young, Choi
AU - Haiil, Ryu
AU - Yong-Son, Kim
SN - 1017-2548
TI - Self-Assembly of Three-Dimensional Copper(II) Macrocyclic Complex with 2,5-Pyridinedicarboxylate Linked by Hydrogen Bond
VL - 47
PB - Korean Chemical Society
DO - 10.5012/jkcs.2003.47.2.104
PY - 2003
UR - http://dx.doi.org/10.5012/jkcs.2003.47.2.104
ER -
Ki-Young, C.
,
Haiil, R.
,
&
Yong-Son, K.
( 2003).
Self-Assembly of Three-Dimensional Copper(II) Macrocyclic Complex with 2,5-Pyridinedicarboxylate Linked by Hydrogen Bond.
Journal of the Korean Chemical Society,
47
(2)
Korean Chemical Society.
doi:10.5012/jkcs.2003.47.2.104
Ki-Young, C
,
Haiil, R
,
&
Yong-Son, K
2003,
Self-Assembly of Three-Dimensional Copper(II) Macrocyclic Complex with 2,5-Pyridinedicarboxylate Linked by Hydrogen Bond,
Journal of the Korean Chemical Society,
vol. 2,
no. 2,
Retrieved from http://dx.doi.org/10.5012/jkcs.2003.47.2.104
[1]
C Ki-Young
,
R Haiil
,
and
K Yong-Son
,
“Self-Assembly of Three-Dimensional Copper(II) Macrocyclic Complex with 2,5-Pyridinedicarboxylate Linked by Hydrogen Bond”,
Journal of the Korean Chemical Society,
vol. 2,
no. 2,
Apr
2003.
Ki-Young, Choi
and
,
Haiil, Ryu
and
,
Yong-Son, Kim
and
,
“Self-Assembly of Three-Dimensional Copper(II) Macrocyclic Complex with 2,5-Pyridinedicarboxylate Linked by Hydrogen Bond”
Journal of the Korean Chemical Society,
2.
2
2003:
Ki-Young, C
,
Haiil, R
,
Yong-Son, K
Self-Assembly of Three-Dimensional Copper(II) Macrocyclic Complex with 2,5-Pyridinedicarboxylate Linked by Hydrogen Bond.
Journal of the Korean Chemical Society
[Internet].
2003.
Apr ;
2
(2)
Available from http://dx.doi.org/10.5012/jkcs.2003.47.2.104
Ki-Young, Choi
,
Haiil, Ryu
,
and
Yong-Son, Kim
,
“Self-Assembly of Three-Dimensional Copper(II) Macrocyclic Complex with 2,5-Pyridinedicarboxylate Linked by Hydrogen Bond.”
Journal of the Korean Chemical Society
2
no.2
()
Apr,
2003):
http://dx.doi.org/10.5012/jkcs.2003.47.2.104
