The expanded uncertainties calculated by the application of GUM -approximation and Monte-Carlo simulation were compared about the model equation of one-point calibration which is widely used for the measurements and chemical analysis. For the comparisons, we assumed a set of artificial data at the various level of concentration and dispersion of t or normal distribution. Mistakes of more then 50 % was revealed at the values calculated by GUM-approximation in comparison with those of Monte-Carlo simulation because of the excess dispersion from t-distribution and non-linearity by division in the equation. In contrary, the mistake of calculation due to non-linearity of the equation was not observed in the level of detection limits with the equation of one-point calibration, because of the relatively large values of uncertainty in response.
@article{ JCGMDC_2003_v47n1_31}
,title={A Study on Comparison between the Propagation of Uncertainty by GUM and Monte-Carlo Simulation}
,volume={1}
, url={http://dx.doi.org/10.5012/jkcs.2003.47.1.031}, DOI={10.5012/jkcs.2003.47.1.031}
, number= {1}
, journal={Journal of the Korean Chemical Society}
, publisher={Korean Chemical Society}
, author={Jungkee, Shu
and
Hyungsik, Min
and
Minsu, Park
and
Jin-Chun, Woo
and
Jongsang, Kim}
, year={2003}
, month={Feb}
TY - JOUR
T2 - Journal of the Korean Chemical Society
AU - Jungkee, Shu
AU - Hyungsik, Min
AU - Minsu, Park
AU - Jin-Chun, Woo
AU - Jongsang, Kim
SN - 1017-2548
TI - A Study on Comparison between the Propagation of Uncertainty by GUM and Monte-Carlo Simulation
VL - 47
PB - Korean Chemical Society
DO - 10.5012/jkcs.2003.47.1.031
PY - 2003
UR - http://dx.doi.org/10.5012/jkcs.2003.47.1.031
ER -
Jungkee, S.
,
Hyungsik, M.
,
Minsu, P.
,
Jin-Chun, W.
,
&
Jongsang, K.
( 2003).
A Study on Comparison between the Propagation of Uncertainty by GUM and Monte-Carlo Simulation.
Journal of the Korean Chemical Society,
47
(1)
Korean Chemical Society.
doi:10.5012/jkcs.2003.47.1.031
Jungkee, S
et al.
2003,
A Study on Comparison between the Propagation of Uncertainty by GUM and Monte-Carlo Simulation,
Journal of the Korean Chemical Society,
vol. 1,
no. 1,
Retrieved from http://dx.doi.org/10.5012/jkcs.2003.47.1.031
[1]
S Jungkee
,
M Hyungsik
,
P Minsu
,
W Jin-Chun
,
and
K Jongsang
,
“A Study on Comparison between the Propagation of Uncertainty by GUM and Monte-Carlo Simulation”,
Journal of the Korean Chemical Society,
vol. 1,
no. 1,
Feb
2003.
Jungkee, Shu
Hyungsik, Min
Minsu, Park
et al.
“A Study on Comparison between the Propagation of Uncertainty by GUM and Monte-Carlo Simulation”
Journal of the Korean Chemical Society,
1.
1
2003:
Jungkee, S
,
Hyungsik, M
,
Minsu, P
,
Jin-Chun, W
,
Jongsang, K
A Study on Comparison between the Propagation of Uncertainty by GUM and Monte-Carlo Simulation.
Journal of the Korean Chemical Society
[Internet].
2003.
Feb ;
1
(1)
Available from http://dx.doi.org/10.5012/jkcs.2003.47.1.031
Jungkee, Shu
,
Hyungsik, Min
,
Minsu, Park
,
Jin-Chun, Woo
,
and
Jongsang, Kim
,
“A Study on Comparison between the Propagation of Uncertainty by GUM and Monte-Carlo Simulation.”
Journal of the Korean Chemical Society
1
no.1
()
Feb,
2003):
http://dx.doi.org/10.5012/jkcs.2003.47.1.031