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Fe-H…H-C Dihydrogen Bondings: Synthesis and Structure of trans-[FeH(NCSe)(dppe)<sub>2</sub>](dppe
Fe-H…H-C Dihydrogen Bondings: Synthesis and Structure of trans-[FeH(NCSe)(dppe)2](dppe
Journal of the Korean Chemical Society. 2002. Oct, 46(5): 427-436
  • Published : October 20, 2002
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Baek, Ji Yeong
Han, Won Seok
Lee, Sun Won

Abstract
Reaction of $trans-[FeHCl(dppe)_2]$ (1) with KSeCN led to the formation of $trans-[FeH(NCSe)(dppe)_2](2).$ Compound 2 $��CH_2Cl_2$ was structurally characterized by X-ray diffraction, in which the hydride ligand appears to be involved in the dihydrogen bonding of the type M-H${\cdot}$${\cdot}$${\cdot}$H-C.
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