It is shown that one-electron reduction of nitric oxide (NO) to nitroxyl anion $(NO^-)$ can be accelerated by vibrational energy. Potential energy surfaces of NO and $NO^-$ reveal that the vertical transition between them has favorable energetics for vibrationally excited molecule. Also, Franck-Condon factors between NO and $NO^-$ vibrational wave functions are calculated. It shows that the number of open channels increases with increased vibrational energy. These results mean that we can control the rate of reduction of NO to $NO^-$ by radiating an appropriate light.
@article{ JCGMDC_2002_v46n1_14}
,title={A Study on the Reduction of Nitric Oxide Molecule (NO) to Nitroxyl Anion (NO-) by Vibrational Energy}
,volume={1}
, url={http://dx.doi.org/10.5012/jkcs.2002.46.1.014}, DOI={10.5012/jkcs.2002.46.1.014}
, number= {1}
, journal={Journal of the Korean Chemical Society}
, publisher={Korean Chemical Society}
, author={Seon-Woog, Cho}
, year={2002}
, month={Feb}
TY - JOUR
T2 - Journal of the Korean Chemical Society
AU - Seon-Woog, Cho
SN - 1017-2548
TI - A Study on the Reduction of Nitric Oxide Molecule (NO) to Nitroxyl Anion (NO-) by Vibrational Energy
VL - 46
PB - Korean Chemical Society
DO - 10.5012/jkcs.2002.46.1.014
PY - 2002
UR - http://dx.doi.org/10.5012/jkcs.2002.46.1.014
ER -
Seon-Woog, C.
( 2002).
A Study on the Reduction of Nitric Oxide Molecule (NO) to Nitroxyl Anion (NO-) by Vibrational Energy.
Journal of the Korean Chemical Society,
46
(1)
Korean Chemical Society.
doi:10.5012/jkcs.2002.46.1.014
&
Seon-Woog, C
2002,
A Study on the Reduction of Nitric Oxide Molecule (NO) to Nitroxyl Anion (NO-) by Vibrational Energy,
Journal of the Korean Chemical Society,
vol. 1,
no. 1,
Retrieved from http://dx.doi.org/10.5012/jkcs.2002.46.1.014
[1]
and
C Seon-Woog
,
“A Study on the Reduction of Nitric Oxide Molecule (NO) to Nitroxyl Anion (NO-) by Vibrational Energy”,
Journal of the Korean Chemical Society,
vol. 1,
no. 1,
Feb
2002.
Seon-Woog, Cho
and
.
“A Study on the Reduction of Nitric Oxide Molecule (NO) to Nitroxyl Anion (NO-) by Vibrational Energy”
Journal of the Korean Chemical Society,
1.
1
2002:
Seon-Woog, C
A Study on the Reduction of Nitric Oxide Molecule (NO) to Nitroxyl Anion (NO-) by Vibrational Energy.
Journal of the Korean Chemical Society
[Internet].
2002.
Feb ;
1
(1)
Available from http://dx.doi.org/10.5012/jkcs.2002.46.1.014
and
Seon-Woog, Cho
.
“A Study on the Reduction of Nitric Oxide Molecule (NO) to Nitroxyl Anion (NO-) by Vibrational Energy.”
Journal of the Korean Chemical Society
1
no.1
()
Feb,
2002):
http://dx.doi.org/10.5012/jkcs.2002.46.1.014