The hydrothermal reaction between lanthanum(��) nitrate $(La(NO3)3${\cdot}$6H_2O)$ and benzene-1,3-dicarboxylic acid $(H_2BDC)$ in the presence of 1,2-bis(4-pyridyl)ethane gave a 2-D lanthnum-BDC coordination polymer with an empirical formula of $��La_4$(BDC)_6(H_2O)_5$��(H_2O)$ (1). X-ray structure analysis of compound 1 revealed that this polymer contains four distinct La metals. The three La metals are 7-coordinate with three different structures: a capped trigonal prism, a capped octahedron, and a pentagonal bipyramid. The remaining La metal has a 8-coordinate, square antiprismatic structure.??��???????M???�?
Citing 'Two-Dimensional Lanthanum-BDC Coordination Polymer:Hydrothermal Synthesis and Structure of [La4(BDC)6(H2O)5](H2O)(BDC
'
@article{ JCGMDC_2001_v45n6_507}
,title={Two-Dimensional Lanthanum-BDC Coordination Polymer:Hydrothermal Synthesis and Structure of [La4(BDC)6(H2O)5](H2O)(BDC}
,volume={6}
, number= {6}
, journal={Journal of the Korean Chemical Society}
, publisher={Korean Chemical Society}
, author={Hye Jin, Kim
and
Dong Won, Min
and
Hyun Su, Heo
and
Soon W., Lee}
, year={2001}
, month={Dec}
TY - JOUR
T2 - Journal of the Korean Chemical Society
AU - Hye Jin, Kim
AU - Dong Won, Min
AU - Hyun Su, Heo
AU - Soon W., Lee
SN - 1017-2548
TI - Two-Dimensional Lanthanum-BDC Coordination Polymer:Hydrothermal Synthesis and Structure of [La4(BDC)6(H2O)5](H2O)(BDC
VL - 45
PB - Korean Chemical Society
PY - 2001
ER -
Hye Jin, K.
,
Dong Won, M.
,
Hyun Su, H.
,
&
Soon W., L.
( 2001).
Two-Dimensional Lanthanum-BDC Coordination Polymer:Hydrothermal Synthesis and Structure of [La4(BDC)6(H2O)5](H2O)(BDC.
Journal of the Korean Chemical Society,
45
(6)
Korean Chemical Society.
Hye Jin, K
,
Dong Won, M
,
Hyun Su, H
,
&
Soon W., L
2001,
Two-Dimensional Lanthanum-BDC Coordination Polymer:Hydrothermal Synthesis and Structure of [La4(BDC)6(H2O)5](H2O)(BDC,
Journal of the Korean Chemical Society,
vol. 6,
no. 6,
[1]
K Hye Jin
,
M Dong Won
,
H Hyun Su
,
and
L Soon W.
,
“Two-Dimensional Lanthanum-BDC Coordination Polymer:Hydrothermal Synthesis and Structure of [La4(BDC)6(H2O)5](H2O)(BDC”,
Journal of the Korean Chemical Society,
vol. 6,
no. 6,
Dec
2001.
Hye Jin, Kim
Dong Won, Min
Hyun Su, Heo
et al.
“Two-Dimensional Lanthanum-BDC Coordination Polymer:Hydrothermal Synthesis and Structure of [La4(BDC)6(H2O)5](H2O)(BDC”
Journal of the Korean Chemical Society,
6.
6
2001:
Hye Jin, K
,
Dong Won, M
,
Hyun Su, H
,
Soon W., L
Two-Dimensional Lanthanum-BDC Coordination Polymer:Hydrothermal Synthesis and Structure of [La4(BDC)6(H2O)5](H2O)(BDC.
Journal of the Korean Chemical Society
[Internet].
2001.
Dec ;
6
(6)
Hye Jin, Kim
,
Dong Won, Min
,
Hyun Su, Heo
,
and
Soon W., Lee
,
“Two-Dimensional Lanthanum-BDC Coordination Polymer:Hydrothermal Synthesis and Structure of [La4(BDC)6(H2O)5](H2O)(BDC.”
Journal of the Korean Chemical Society
6
no.6
()
Dec,
2001):
