The combinatorial approach has been applied to discover and optimize the composition of the novel or enhanced materials. In this study, we screened the optimum composition of the system SrO-Gd$_2$O$_3$-Al$_2$O$_3$ doped with $Tb^{3+}$ by a polymerized-complex combinatorial chemistry method. Mixtures with compositions of Sr, Gd and Al component that is in the range from 0 to 1 in about 0.05 increments could be tested. The sample powders were synthesized by a polymerized complex method. To prepare appropriately polymeric precursors, we used the metallic nitrates, citric acid and ethylene glycol. The luminescence properties of the synthesized powders are investigated using the UV and VUV (Vacuum-UV: 147 nm) photoluminescence spectrometer. In addition, the crystallinity and morphology of powder were monitored by X-ray diffraction spectrometer and scanning electron microscopy. In result of VUV PL works, there are good luminescent samples with the composition of 0.595 < x < 0.733 and 0.016 < y < 0.017 in Gd1-x-yAlxTbyO$\delta$ and 0.049 < x < 0.064 and 0.02 < y < 0.039 in $Sr_xAl_{1-x-y}Tb_yO_$\delta$$, their materials can be applicable to plasma display panels as the green phosphor.
Citing 'Synthesis and Screening of the System $SrO-Gd_2O_3-Al_2O_3$Doped with Tb by Polymerized-Complex Combinatorial Chemistry
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@article{ JCGMDC_2001_v45n5_461}
,title={Synthesis and Screening of the System $SrO-Gd_2O_3-Al_2O_3$Doped with Tb by Polymerized-Complex Combinatorial Chemistry}
,volume={5}
, number= {5}
, journal={Journal of the Korean Chemical Society}
, publisher={Korean Chemical Society}
, author={Yang Sun, Jeong
and
Chang Hae, Kim
and
Hee Dong, Park
and
Joon Taik, Park
and
Sung Kwon, Kang}
, year={2001}
, month={Oct}
TY - JOUR
T2 - Journal of the Korean Chemical Society
AU - Yang Sun, Jeong
AU - Chang Hae, Kim
AU - Hee Dong, Park
AU - Joon Taik, Park
AU - Sung Kwon, Kang
SN - 1017-2548
TI - Synthesis and Screening of the System $SrO-Gd_2O_3-Al_2O_3$Doped with Tb by Polymerized-Complex Combinatorial Chemistry
VL - 45
PB - Korean Chemical Society
PY - 2001
ER -
Yang Sun, J.
,
Chang Hae, K.
,
Hee Dong, P.
,
Joon Taik, P.
,
&
Sung Kwon, K.
( 2001).
Synthesis and Screening of the System $SrO-Gd_2O_3-Al_2O_3$Doped with Tb by Polymerized-Complex Combinatorial Chemistry.
Journal of the Korean Chemical Society,
45
(5)
Korean Chemical Society.
Yang Sun, J
et al.
2001,
Synthesis and Screening of the System $SrO-Gd_2O_3-Al_2O_3$Doped with Tb by Polymerized-Complex Combinatorial Chemistry,
Journal of the Korean Chemical Society,
vol. 5,
no. 5,
[1]
J Yang Sun
,
K Chang Hae
,
P Hee Dong
,
P Joon Taik
,
and
K Sung Kwon
,
“Synthesis and Screening of the System $SrO-Gd_2O_3-Al_2O_3$Doped with Tb by Polymerized-Complex Combinatorial Chemistry”,
Journal of the Korean Chemical Society,
vol. 5,
no. 5,
Oct
2001.
Yang Sun, Jeong
Chang Hae, Kim
Hee Dong, Park
et al.
“Synthesis and Screening of the System $SrO-Gd_2O_3-Al_2O_3$Doped with Tb by Polymerized-Complex Combinatorial Chemistry”
Journal of the Korean Chemical Society,
5.
5
2001:
Yang Sun, J
,
Chang Hae, K
,
Hee Dong, P
,
Joon Taik, P
,
Sung Kwon, K
Synthesis and Screening of the System $SrO-Gd_2O_3-Al_2O_3$Doped with Tb by Polymerized-Complex Combinatorial Chemistry.
Journal of the Korean Chemical Society
[Internet].
2001.
Oct ;
5
(5)
Yang Sun, Jeong
,
Chang Hae, Kim
,
Hee Dong, Park
,
Joon Taik, Park
,
and
Sung Kwon, Kang
,
“Synthesis and Screening of the System $SrO-Gd_2O_3-Al_2O_3$Doped with Tb by Polymerized-Complex Combinatorial Chemistry.”
Journal of the Korean Chemical Society
5
no.5
()
Oct,
2001):