The Fe(II)-isothiocyanato complex $trans-[FeH(NCS)(dppe)_2]$ (1) eactedwith iodomethane(Mel) to give methyl isothiocyanide-Fe(n) complex, $trans-FeH(NCS(Me)-S)(dppe)_2]I(2)$. Compound 2 was oxidized to $trans-[Fe(NCS)_2(Ph_2P(O)CH_2CH_2P(O)Ph_2)_2][I_3]$ (3), which was structurally characterized by X-ray diffraction. The molecular structure of 3 showed a bent Fe-NCS group, Crystallographic data for 3: triclinic space group P1,a=11.071(2) A,b=12.054(2)A,c=12.121(1)A, $\alpha=101.02(1){\circ}C{\beta}=95.887(9){\circ}Cr=110.34(1){\circ}C$, $Z=1R(wR_2)=0.0567(0.1294)$.
Citing 'Oxidation of trans-[FeH(NCS(Me)-S)(dppe)2]I to trans trans-[FeNCS)2(Ph2P(O)CH2CH2P(O)Ph2)2][I3](dppe
'
@article{ JCGMDC_2000_v44n4_311}
,title={Oxidation of trans-[FeH(NCS(Me)-S)(dppe)2]I to trans trans-[FeNCS)2(Ph2P(O)CH2CH2P(O)Ph2)2][I3](dppe}
,volume={4}
, number= {4}
, journal={Journal of the Korean Chemical Society}
, publisher={Korean Chemical Society}
, author={Ji Hwa, Lee
and
Soon W., Lee}
, year={2000}
, month={Aug}
TY - JOUR
T2 - Journal of the Korean Chemical Society
AU - Ji Hwa, Lee
AU - Soon W., Lee
SN - 1017-2548
TI - Oxidation of trans-[FeH(NCS(Me)-S)(dppe)2]I to trans trans-[FeNCS)2(Ph2P(O)CH2CH2P(O)Ph2)2][I3](dppe
VL - 44
PB - Korean Chemical Society
PY - 2000
ER -
Ji Hwa, L.
,
&
Soon W., L.
( 2000).
Oxidation of trans-[FeH(NCS(Me)-S)(dppe)2]I to trans trans-[FeNCS)2(Ph2P(O)CH2CH2P(O)Ph2)2][I3](dppe.
Journal of the Korean Chemical Society,
44
(4)
Korean Chemical Society.
Ji Hwa, L
,
&
Soon W., L
2000,
Oxidation of trans-[FeH(NCS(Me)-S)(dppe)2]I to trans trans-[FeNCS)2(Ph2P(O)CH2CH2P(O)Ph2)2][I3](dppe,
Journal of the Korean Chemical Society,
vol. 4,
no. 4,
[1]
L Ji Hwa
,
and
L Soon W.
,
“Oxidation of trans-[FeH(NCS(Me)-S)(dppe)2]I to trans trans-[FeNCS)2(Ph2P(O)CH2CH2P(O)Ph2)2][I3](dppe”,
Journal of the Korean Chemical Society,
vol. 4,
no. 4,
Aug
2000.
Ji Hwa, Lee
and
,
Soon W., Lee
and
,
“Oxidation of trans-[FeH(NCS(Me)-S)(dppe)2]I to trans trans-[FeNCS)2(Ph2P(O)CH2CH2P(O)Ph2)2][I3](dppe”
Journal of the Korean Chemical Society,
4.
4
2000:
Ji Hwa, L
,
Soon W., L
Oxidation of trans-[FeH(NCS(Me)-S)(dppe)2]I to trans trans-[FeNCS)2(Ph2P(O)CH2CH2P(O)Ph2)2][I3](dppe.
Journal of the Korean Chemical Society
[Internet].
2000.
Aug ;
4
(4)
Ji Hwa, Lee
,
and
Soon W., Lee
,
“Oxidation of trans-[FeH(NCS(Me)-S)(dppe)2]I to trans trans-[FeNCS)2(Ph2P(O)CH2CH2P(O)Ph2)2][I3](dppe.”
Journal of the Korean Chemical Society
4
no.4
()
Aug,
2000):
