Electrodes of the polycationic film with electropolymerized $[Ru(v-bpy)_3]^{2+}$ having about 1:1 ratio of $PF6^-/ClO_4^-$as the doped counter ions, were modified with xylenol orange and diethylditbiocarbamate by ion exchange which had stability constant as 38.6 and 17.5 respectively. These electrodes were employed in the quantitative multiple determination of U(W) in solution. The working electrode of electrochemical cell for the analytical signal was Pt/p-$[Ru(v-bpy)_3]^{2+}$, ligand, U(VI) with Ag/AgCl reference elecrode. In the stripping voltammetry. electrode process was electron transfer controlled one and calibration curves at the ranges of $1.0{\times}10^{-3}{\sim}1.0{\times}10^{-7}$ M had excellent relationship as 0.99 and relative standard deviation as 5${\sim}$8%.
Citing 'Quantitative Determination of $UO2^{2+}$ with Modified $[Ru(v-bpy)_3]^{2+}$ Polymer Film Electrode
'
@article{ JCGMDC_2000_v44n1_17}
,title={Quantitative Determination of $UO2^{2+}$ with Modified $[Ru(v-bpy)_3]^{2+}$ Polymer Film Electrode}
,volume={1}
, number= {1}
, journal={Journal of the Korean Chemical Society}
, publisher={Korean Chemical Society}
, author={Seong-Keuck, Cha}
, year={2000}
, month={Feb}
TY - JOUR
T2 - Journal of the Korean Chemical Society
AU - Seong-Keuck, Cha
SN - 1017-2548
TI - Quantitative Determination of $UO2^{2+}$ with Modified $[Ru(v-bpy)_3]^{2+}$ Polymer Film Electrode
VL - 44
PB - Korean Chemical Society
PY - 2000
ER -
Seong-Keuck, C.
( 2000).
Quantitative Determination of $UO2^{2+}$ with Modified $[Ru(v-bpy)_3]^{2+}$ Polymer Film Electrode.
Journal of the Korean Chemical Society,
44
(1)
Korean Chemical Society.
&
Seong-Keuck, C
2000,
Quantitative Determination of $UO2^{2+}$ with Modified $[Ru(v-bpy)_3]^{2+}$ Polymer Film Electrode,
Journal of the Korean Chemical Society,
vol. 1,
no. 1,
[1]
and
C Seong-Keuck
,
“Quantitative Determination of $UO2^{2+}$ with Modified $[Ru(v-bpy)_3]^{2+}$ Polymer Film Electrode”,
Journal of the Korean Chemical Society,
vol. 1,
no. 1,
Feb
2000.
Seong-Keuck, Cha
and
.
“Quantitative Determination of $UO2^{2+}$ with Modified $[Ru(v-bpy)_3]^{2+}$ Polymer Film Electrode”
Journal of the Korean Chemical Society,
1.
1
2000:
Seong-Keuck, C
Quantitative Determination of $UO2^{2+}$ with Modified $[Ru(v-bpy)_3]^{2+}$ Polymer Film Electrode.
Journal of the Korean Chemical Society
[Internet].
2000.
Feb ;
1
(1)
and
Seong-Keuck, Cha
.
“Quantitative Determination of $UO2^{2+}$ with Modified $[Ru(v-bpy)_3]^{2+}$ Polymer Film Electrode.”
Journal of the Korean Chemical Society
1
no.1
()
Feb,
2000):
