Extended Huckel Molecular Orbital (EHMO) calculations of haloallene (1-halo-3-phenyl-1,2-propadiene) derivatives have been performed. From the MO calculation data and kinetic experimental results, the mechanism for the hydrolysis of haloallenes is proposed.; Below pH 8.0, the hydrolysis proceeds through a solvent assisted $S_N1$ mechanism involving the formation of carbonium ion �� as intermediate. However above pH 9.5, the hydrolysis proceeds through an $S_N2'$ mechanism via transition state ��.?????????????????? 6??��???????5???????
Citing 'Kinetics and Mechanism of the Hydrolysis of 1-Halo-3-Phenyl-1,2-Propadienes
'
@article{ JCGMDC_1997_v41n7_351}
,title={Kinetics and Mechanism of the Hydrolysis of 1-Halo-3-Phenyl-1,2-Propadienes}
,volume={7}
, number= {7}
, journal={Journal of the Korean Chemical Society}
, publisher={Korean Chemical Society}
, author={Kang Ryul, Lee
and
Hil Ra, Yoo
and
In Chan, Jung
and
Tae Sung, Huh}
, year={1997}
, month={Jul}
TY - JOUR
T2 - Journal of the Korean Chemical Society
AU - Kang Ryul, Lee
AU - Hil Ra, Yoo
AU - In Chan, Jung
AU - Tae Sung, Huh
SN - 1017-2548
TI - Kinetics and Mechanism of the Hydrolysis of 1-Halo-3-Phenyl-1,2-Propadienes
VL - 41
PB - Korean Chemical Society
PY - 1997
ER -
Kang Ryul, L.
,
Hil Ra, Y.
,
In Chan, J.
,
&
Tae Sung, H.
( 1997).
Kinetics and Mechanism of the Hydrolysis of 1-Halo-3-Phenyl-1,2-Propadienes.
Journal of the Korean Chemical Society,
41
(7)
Korean Chemical Society.
Kang Ryul, L
,
Hil Ra, Y
,
In Chan, J
,
&
Tae Sung, H
1997,
Kinetics and Mechanism of the Hydrolysis of 1-Halo-3-Phenyl-1,2-Propadienes,
Journal of the Korean Chemical Society,
vol. 7,
no. 7,
[1]
L Kang Ryul
,
Y Hil Ra
,
J In Chan
,
and
H Tae Sung
,
“Kinetics and Mechanism of the Hydrolysis of 1-Halo-3-Phenyl-1,2-Propadienes”,
Journal of the Korean Chemical Society,
vol. 7,
no. 7,
Jul
1997.
Kang Ryul, Lee
Hil Ra, Yoo
In Chan, Jung
et al.
“Kinetics and Mechanism of the Hydrolysis of 1-Halo-3-Phenyl-1,2-Propadienes”
Journal of the Korean Chemical Society,
7.
7
1997:
Kang Ryul, L
,
Hil Ra, Y
,
In Chan, J
,
Tae Sung, H
Kinetics and Mechanism of the Hydrolysis of 1-Halo-3-Phenyl-1,2-Propadienes.
Journal of the Korean Chemical Society
[Internet].
1997.
Jul ;
7
(7)
Kang Ryul, Lee
,
Hil Ra, Yoo
,
In Chan, Jung
,
and
Tae Sung, Huh
,
“Kinetics and Mechanism of the Hydrolysis of 1-Halo-3-Phenyl-1,2-Propadienes.”
Journal of the Korean Chemical Society
7
no.7
()
Jul,
1997):
