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A New Anthracene Based Fluorescent Turn-On Sensor for Fe<sup>3+</sup>
A New Anthracene Based Fluorescent Turn-On Sensor for Fe3+
Bulletin of the Korean Chemical Society. 2014. Jan, 35(1): 277-279
Copyright © 2014, Korea Chemical Society
  • Received : September 10, 2013
  • Accepted : October 13, 2013
  • Published : January 20, 2014
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About the Authors
Kyoung-Lyong An
Interface Chemistry & Engineering Research Team, Korea Research Institute of Chemical Technology, Daejeon 305-600, Korea
Sang-Oh Lee
Department of Chemistry, Chungnam National University, Daejeon 305-764, Korea
Sun Duk Koh
Department of Chemistry, Chungnam National University, Daejeon 305-764, Korea
Seung-Rim Shin
Department of Chemistry, Chungnam National University, Daejeon 305-764, Korea
Jong-Il Shin
Department of Chemistry, Chungnam National University, Daejeon 305-764, Korea
Soo-Youl Park
Department of Chemistry, Chungnam National University, Daejeon 305-764, Korea
Young-A Son
Department of Advanced Organic Materials Engineering, Chungnam National University, Daejeon 305-764, Korea
Koon Ha Park
Interface Chemistry & Engineering Research Team, Korea Research Institute of Chemical Technology, Daejeon 305-600, Korea
Kun Jun
Department of Chemistry, Chungnam National University, Daejeon 305-764, Korea

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Experimental
Synthesis of 1. To a solution of 3-amino-1-propanol 1.28 g (17mmol) in anhydrous dimethylsulfoxide (30 mL) under nitrogen atmosphere, was added slowly 9,10-bis(chloromethyl)anthracene 0.90 g (3.3 mmol) at room temperature. After stirring for 6 h, water (70 mL) was poured into the reaction mixture. Then the product was extracted by dichloromethane. The combined organic layer was dried with anhydrous sodium sulfate and the solution was evaporated to dryness. The crude product washed with acetone to give 0.65 g (56%, pale yellow solid) of 1 . 1 H NMR (DMSO- d6 ) δ 1.63 (4H, qt), 2.83 (4H, t), 3.47 (4H, t), 4.58 (4H, s), 7.53 (4H, dd), 8.41 (4H, dd), MS (m/e): 352, HRMS: calcd. for M+ (C 22 H 28 N 2 O 2 ) 352.2151, found 352.2147.
Acknowledgements
This work was supported by Institutional Research Program of Korea Research Institute of Chemical Technology (KRICT) and the R&D Program of Small & Medium Business Administration (SMBA).
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