Thermostable Adsorption Filter Immobilized with Super Activated Carbons by Quinoline Soluble Isotropic Pitch Binder (I-a Novel Adsorption Filter)
Thermostable Adsorption Filter Immobilized with Super Activated Carbons by Quinoline Soluble Isotropic Pitch Binder (I-a Novel Adsorption Filter)
Carbon letters. 2009. Sep, 10(3): 198-201
Copyright ©2009, Korean Carbon Society
  • Received : January 22, 2009
  • Accepted : August 10, 2009
  • Published : September 30, 2009
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About the Authors
Yeong Tae, Park
Dongyang Carbon Co. Ltd., Balsanri 355, Susinmyeon, Cheonan, Chungnam 330-881, Korea
Chul Gyou, Im
Dongyang Carbon Co. Ltd., Balsanri 355, Susinmyeon, Cheonan, Chungnam 330-881, Korea
Yeong Tae, Kim
Dongyang Carbon Co. Ltd., Balsanri 355, Susinmyeon, Cheonan, Chungnam 330-881, Korea
Bo Sung, Rhee
Dept. of Chem. Eng., Chungnam Natl. Univ., Yuseong, Daejon 305-764, Korea

Among other filters such as light filter, wave filter, air filter, ultra filter and filter paper, a novel adsorption filter from thermostable polyester nonwoven fabrics immobilized with functional super activated carbon by means of quinoline soluble, activateable isotropic pitch binder were developed in this study. The activated carbon precursor is available in the market branded as coconut shell based activated carbon(CCS-AC) produced by Dongyang Carbon Co. Ltd. BET-surface area of this precursor was 1,355 m 2 /g, after KOH-activation it increased over 2,970 m 2 /g and was named as super activated carbon. In the preliminary research, this precursor was impregnated with PdCl 2 (0.188 wt%) KMnO 4 (3 wt%) and redox-agent(CuCl2,0.577 wt%) in order to promote TOF up to 100/h and Selectivity up 99% and patented as a functional AC for the ethylene adsorption. The enhancement of the isotropic pitch binder to the AC-immobilized adsorption filter was BET-surface area upgraded by 266 m 2 /g and promoted the Iodine- and MB-adsorption by 1.4 times, respectively and also micro pore wide ranges <5Å~30 Å>.
1. Introduction
The two main air pollution problems in Korea at present are sick building syndrome and high temperature CO gas occurred in subway accidents, in the later case we and also accompanied animals shall outfit with civilian gasmasks composed of AC-immobilized adsorption filter packs. News also announced that the most of the outfits are defected. So a novel idea is suggested to overcome these problems.
So called high BET-surface area over 3,000 m 2 /g in the activated carbons were patented by A. N. Wennerberg, US Patent 4082694 [1] and F. J. Derbyshire, US Patent Documents 6057262 [2] with coal cokes based activated carbons in abroad and 2,800 m 2 /g reported by H.K. Jin with coconut shell based activated carbons in inland [3] . But they all have studied with solid-solid contact reaction(Film Model) composed of Carbon-KOH(anhydrous). However in this study we have prepared it carefully with solid-liquid diffusion controlled reaction (Penetration Model) composed of Carbon-KOH(strong elec-trolyte saturated solution, 97 g/100H 2 O).
We have also prepared a thermostable PE-nonwoven fabric for the moderate temperature (320) usage by means of continuous 3 steps different thermal treatment processes, impregnated it with a AC-QS(Activated Carbon-Quinoline Solubles of Petroleum Isotropic Pitch [4] ) slurry mixtures and dried at the temperature 240℃, followed by the reactivation process at the higher temperature (400~700℃) in order to enhance the surface area and the micro pores ranges in the targeted adsorption filters. For the higher temperature over 700℃ we have applied Sigri-Thermospelz (nonwoven fabrics of pitch fibers made by Sigri, Germany), immobilized with super AC by means of isotropic pitch binder and reactivated up to 30%-burn off with hot steam-activation at 900℃. These are named a novel idea of AC-Immobilized Adsorption Filters in this study.
2. Experimental
Super activated carbons were prepared with coconut shell based AC made of the commercially available coconut shell char, as the precursor, by impregnation with saturated solution of KOH into AC followed by dehydration under 320℃ and chemical activation at high temperature (900℃) with increasing additions from 1/1 to 1/5 of AC/KOH-mass ratios. For the thermal-stable PE-nonwoven fabrics and the KOH-activation, we have developed two heating and holding time programs [see, a) mechanism of KOH-activation, b) & c) 2 temperature programs] and constructed a continuous 3 zone
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A continuous 3 zone thermal treatment furnaces for polyester nonwoven fabrics: a) input and b) output zone.
thermal treatment furnace as shown in Fig 1 a) Input of white color PE-nonwoven fabric into first zone and b) Output of brown color thermal stable fabric from the third zone in accordance to the thermal analysis as Fig. 2 .(DSC-TGA diagram).
In order to increase the TOF the ACs were impregnated with 0.188 wt% PdCl 2 and 0.577 wt% CuCl 2 , 3 wt% KMnO 4 , respectively [5 , 6]
  • a) Mechanism of KOH-Activation:
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  • b) Continuous Process: Temperature Program of Thermal Treatment with PE-nonwoven fabrics:
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Thermal analysis of PE-nonwoven fabrics.
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  • c) Batch process: Temperature Program of KOH-Activation
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Thermostable PE-nonwoven fabrics for the moderate temperature were prepared with the polyester nonwoven fabrics which are available in the market by means of 3 stepthermal treatment program from 100℃ via 180℃ to 320℃ in atmospheric environments continuously. For high temperatures above 700℃, Sigri-Thermospelz, which are available in Germany market were applied without pretreatments.
AC-immobilized adsorption filters were prepared with the thermostable nonwoven fabrics and also Sigri-Thermospelz by coating AC-epoxy resin binder (degree of Polymerization ca.300) mixture and AC-QS (Quinoline Solubles of Isotropic Pitch binder, B.Pt. ca. 360℃) mixture, respectively and drying at 240℃ followed by reactivation at 900℃ in order to disclose coated surface areas and micro pores in the Thermospelz-filters. Particularly, isotropic pitch binder was developed from petroleum pitch [4] and dissolved by Quinoline, namely QS and AC were impregnated into the thermostable PE-nonwoven fabrics followed by drying and reactivation to product AC- immobilized filters.
Enhancement effects of isotropic pitch binders to the surface area and adsorptivity of AC-immobilized adsorption filter were tested by BET-analysis, Iodine- and methylene blue MB-adsorption as the model pollutant using the
BET Surface Areas and Volumes Absorbed of Various Activated Carbon Precursors
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BET Surface Areas and Volumes Absorbed of Various Activated Carbon Precursors
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KOH-Activation effects of coconut shell activated carbon on the BET-Surface areas and volume adsorbed.
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a) PE-nonwoven fabrics b) thermostable fabrics c)Sigri-thermospelz d~f) their AC-immobilized adsorption filters and :a’~ f’) thier magnification of SEM photos.
correlativity between S BET , I 2 - and MB-adsorptions [7] . Adsorptive tests for the Betrex of this developed filter will be reported in the second publication.
3. Results and Discussion
Table 1 shows the results of BET-analysis of the activated carbon including of coconut shell char (S-BET: 298 m 2 /g)
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BET-analysis of the AC-immobilized adsorption filter after KOH-activation with C:H-mass ratio of 1:1.
which were used to convert into activated carbon (1,355 m 2 /g) and applied to the KOH-activation in this work. After KOHactivation shows the increasing BET surface areas of coconut shell AC in accordance to addition of AC/KOH mass ratio [ Fig.3 a) increasing S BET =1,300~1,900 from 1/0 to 1/2; b) 2,200 ~ 2900 m 2 from 1/3 to 1/5 with mass ratios of C/KOH] It was confirmed that increasing rate of BETsurface area was 300 m 2 /g and limited max. 2970 m 2 /g was in case of the mass ratio 1/5 of AC/KOH with the coconut shell activated carbon.
Fig. 4 shows photos from white color PE-nonwoven fabrics(a), its brown color thermostable PE-nonwoven fabrics(b) and black color of Sigri-thermospelz(c) to their SEM picture are (a’), (b’) and (c’). Pictures (d), (e) and (f)
Isotherm Adsorbed (mg/g STP) of I2(0.02N) and Methylene Blue (0.24 mg/l)(*AC-immobilized &amp; reactivated adsorption filter by means of isotropic pitch binder)
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Isotherm Adsorbed (mg/g STP) of I2 (0.02N) and Methylene Blue (0.24 mg/l) (*AC-immobilized & amp; reactivated adsorption filter by means of isotropic pitch binder)
are the AC-Immobilized adsorption filters by means of epoxy resin and isotropic pitch binders, and their magnifications (d’), (e’), and (f’), respectively.
Fig. 5 shows Enhancements of BET-surface area increased by 270 m 2 /g) and micropore promotion (<5 Å~30 Å>) after reactivation of the AC-Immobilized Adsorption Filter developed in this work by means of isotropic pitch binder.
In the Table 2 , we can confirm that the enhancement effects on the adsorptivity of iodine and methylene blue were each 1.4 times promoted by surface area increase of 266 m 2 /g.
4. Conclusions
In this work we have developed AC-immobilized adsorption filter with thermostable PE-nonwoven fabrics for the moderate temperature and with Sigri-thermospelz for high temperature by means of isotropic pitch binder which enhanced not only surface area, also adsorptivity of Iodineand Methylene blue as the model pollutant. The applied AC was coconut shell based activated carbon which has surface area of 1355 m 2 /g, and enhanced to 2970 m 2 /g by reactivation after the KOH-activation with mass ratio1/5 of C/KOH.
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