A fiber diffuser sheet based on poly (ethylene naphthalate) (PEN) and poly (methylpentene) (PMP) has shown potential for liquid crystal display backlight units, but these materials have an interfacial adhesion problem. To improve the interfacial adhesion between the fibers and matrix components, we have proposed the use of amorphous poly (cyclohexane-1,4-dimethylene terephthalate) (Tritan) instead of PEN. Furthermore, the fabrication processes have been optimized and simplified to improve the optical and mechanical properties of the sheet. As a result, the most effective fiber content for achieving the best haze characteristics of a sample consisting of Tritan and PMP has been identified.
The liquid crystal display (LCD) is one of the most widely employed flat-panel displays in multimedia devices such as mobile phones, computer monitors, televisions, etc.
. In the field of LCDs, many researchers have been making strong efforts to develop backlight units (BLUs) with good optical properties, namely, high luminance, good luminance uniformity, and a wide viewing angle
. In the BLUs, a diffuser sheet that can provide uniform brightness by spreading the light is a key component. Although diffuser sheets have been developed extensively, most research has been on bead-type sheets
. Recently, new optical diffuser sheets based on fiber technology have been studied, and their potential has been demonstrated
. However, detailed studies on diffuser sheets based on fiber technology have not yet been conducted.
In a previous work, poly (ethylene naphthalate) (PEN) and poly (methylpentene) (PMP) were chosen for the fiber and matrix components, respectively, in such a fiber-based diffuser sheet
. Although they showed potential, these materials exhibited an interfacial adhesion problem. As the PEN content was increased, the diffuser sheet crumbled easily. Thus, no optimum ratio of PEN to PMP could be found. In this study, amorphous poly (cyclohexane-1,4-dimethylene terephthalate) (Tritan) was used as the fiber component, which led to improved interfacial adhesion between the matrix and fibers. Then, various fiber contents were examined to find the composition leading to the most effective haze and total transmittance characteristics of this diffuser system.
II. PREVIOUS DIFFUSER SHEET LACKING INTERFACIAL ADHESION
In the previous films
, fabricated by islands-in-the-sea (INS) conjugate melt-spinning
, the PEN and PMP (TPX
RT18, Mitsui Chemical) showed vulnerability to crumpling, depending on the PEN content. In particular, as the PEN content was increased, the diffuser sheet crumbled easily.
shows a diffuser sheet made from PEN and PMP by INS conjugate melt-spinning. After the diffuser sheet was crumpled into a ball, it broke into fragments, as shown in
. To analyze the cause of this phenomenon, we measured the tensile stress-strain curves of a sheet sample consisting of pure PMP and a sample with 40 vol% PEN diffuser. The samples were cut into 2.54 × 100.0 mm strips and preconditioned at 75% relative humidity and 25℃ for 48 h. The tensile properties were measured on an Instron tester (Norwood, MA, USA) according to the ASTM D882 standard. The initial grip separation was set to 50 mm, and the cross-head speed was set to 50 mm/min with a load cell of 50 kgf. At least five identical specimens were measured per experiment. Increasing the PEN fiber content to 40 vol% PEN led to more brittle fracture and lower strains of failure in both the machine direction (MD) and cross direction (CD), as compared to those for pure PMP. The poor durability of the 40 vol% PEN sample can be fully explained by the tensile properties shown in
Diffuser sheet made of the PEN and PMP (TPX® RT18) (a) before and (b) after it was crumpled into a ball. (c) Tensile stress-strain curves of sheets made from pure PMP (TPX® RT18) and 40 vol% PEN. MD and CD indicate, respectively, the machine direction and cross direction.
III. SHEET FABRICATION
In order to fabricate the proposed diffuser sheet with improved interfacial adhesion, amorphous Tritan (Tritan
copolyester TX2001, Eastman) and PMP were used as the fiber and matrix, respectively. Each material was obtained in pellet form and then melted and extruded by a single-screw extruder with temperature profiles of 240℃-277℃ and 200℃-255℃. Under the pressure in the extruder, the melted fiber component passes through a spin pack with 3808 holes and then comes out of the slit-die, which creates the INS film consisting of a large number of individual islands of one polymer surrounded by a sea or matrix of another polymer. Unlike the conventional INS conjugate melt-spinning process, in which the sea polymer has to be removed by dissolving it with a solvent or by melting, a simple INS conjugate melt-spinning process without the dissolution step was focused on here, thereby reducing the number of complex work processes. The resulting film was then wound around the winding roll machine. The respective speeds of the casting roll, cooling roll, and take-off unit were 3, 4, and 6.4 m/min. A schematic illustration of the INS conjugate spinning setup and a photograph of the real spinning setup are shown in
. In contrast to earlier approaches, in this approach a slit-die was utilized instead of a T-die to increase the fiber packing. In addition, the additional stretching process to match the birefringence of the fibers with that of the matrix was not adopted, for convenience of the manufacturing process
, since our focus here was on a simple INS conjugate melt-spinning process.
Schematic illustration of the INS conjugate spinning setup and photograph of the real spinning setup.
IV. RESULTS AND DISCUSSION
Although we did not adopt an additional stretching process, the fabricated diffuser sheet still showed optically isotropic and birefringent characteristics, because some of the elongation necessary to achieve good birefringence was achieved in the winding process. In general, a crossed polarizer condition is utilized to confirm birefringence.
shows the optical isotropy of the pure PMP (TPX
RT18) sample. On the other hand,
shows the birefringence of the sample with a 30 vol% Tritan fiber content. According to the Jones matrix method, the transmittance of a sample placed at an azimuth angle Ψ with respect to the transmission axes of the crossed polarizers will behave as follows
Fabricated samples: (a) isotropy of the sample with 100 vol% PMP and (b) birefringence of the sample with 30 vol% Tritan. The arrows indicate the directions of the polarizers.
The obtained transmittance for Ψ = 45° is then given as
where Γ is the phase retardation,
is the birefringence, and
is the thickness. When Ψ= 45°, maximum brightness is achieved, whereas
= 0 when Ψ= 0° or 90°. Therefore, an angle of Ψ= 45° was used to obtain the bright state in
shows the cross-sectional view of the fabricated diffuser sheets based on Tritan fiber and the PMP matrix. The morphology was observed by using a scanning electron microscope (SEM) (SU810, Hitachi, Japan). An image analysis technique was used to quantify the characteristic sizes of the fibers and their distributions in the proposed diffuser systems.
Scanning electron micrographs of the proposed diffuser sheets consisting of different amounts of Tritan and PMP.
We fabricated nine kinds of diffuser sheets with different fiber contents (10-90 vol% Tritan) by INS conjugate melt-spinning to find the content yielding the best haze and total transmittance characteristics for this diffuser system. As seen in
, the characteristic sizes of the fibers became larger as the fiber content increased. For 10 vol% fiber, fibers of 5 μm in diameter are observed occasionally. At 50 vol% fiber content, fiber diameters of 20 μm are mainly observed. In addition, as the fiber content became larger, the fibers became closer in the matrix, until agglomeration occurred at 70 vol% fiber content because of the larger, closer fibers. These characteristic sizes and distributions of the fibers obviously affected the optical properties of the obtained sheets.
shows the haze characteristics for different fiber contents. The haze was large, above 85.5%, for 30 - 80 vol% fiber content values. Contrary to expectations, the haze values did not continuously increase with fiber content. Above 30 vol%, the haze values were nearly saturated, and a maximum of 87.4% was reached at 60 vol%.
shows the dependence of the total transmittance values on the Tritan fiber content. Although the haze and total transmittance do not always exhibit opposite behavior, they tend to do so in our case: high haze values were associated with low transmittance, and vice versa. When the fiber content was 80 - 90 vol%, the total transmittance unexpectedly increased. In this region, the dispersed fibers assembled with each other in the matrices, and large domains composed of the fiber materials were obtained. Hence, the total transmittance was increased owing to the decrease in scattering between the fibers and matrix components. Consequently, the haze characteristics were also decreased. Thus, taken together, the haze and transmittance both had reasonably high values at a 30 vol% fiber content, of 85.5% and 90.9%, respectively, in this case.
(a) Haze and total transmittance characteristics for different fiber contents.
shows the tensile stress-strain curves of the diffuser PMP sheets with 40 vol% PEN and 30 vol% Tritan. The use of 30 vol% Tritan fiber led to more ductile fracture and increased strain of failure in both the MD and CD, as compared to those obtained with 40 vol% PEN. The improved durability performance of the sample with 30 vol% Tritan can be fully explained by the tensile results in
. The PMP and PEN used previously were semicrystalline thermoplastic polymers, and it is known that combinations of semicrystalline polymers lead to interfacial adhesion problems between the fibers and matrix component. On the other hand, Tritan was well known to be an amorphous copolymer. Thus, from
, it was confirmed that the use of amorphous Tritan instead of semicrystalline PEN effectively improved the interfacial adhesion.
Tensile stress-strain curves of diffuser sheets with 40 vol% PEN and 30 vol% Tritan.
shows angular distributions of the luminance with respect to the angles along the horizontal (0°), diagonal (45°), and vertical (90°) directions of the BLUs with a commercially available diffuser sheet and the fiber-based diffuser sheet fabricated in our study. The angular distributions of the luminance with respect to the angles were measured by using the EZContrast XL88 system (ELDIM). As shown in
, the brightness profile of the BLU with our diffuser sheet was comparable with that of the BLU with the conventional diffuser sheet.
Angular distributions of the luminance with respect to the angles along the horizontal (0°), diagonal (45°), and vertical (90°) directions of the BLUs with (a) a commercially available diffuser sheet and with (b) our fiber-based diffuser sheet fabricated in this work.
In a previous work, we proposed a diffuser sheet based on fiber technology and confirmed the feasibility of this approach. In this work, we made various attempts to improve the optical and mechanical properties of this diffuser system. To improve the interfacial adhesion, amorphous PET copolymer was proposed as the fiber component. To simplify the complex fabrication processes, the dissolution step and additional stretching process were omitted. In addition, a slit-die was utilized instead of a T-die to increase the fiber packing. Then, the most effective fiber content for maximizing the optical performance was identified for samples consisting of amorphous Tritan fibers and a PMP matrix.
The authors would like to express thanks to Yeo Hoon Yoon, Hyun Kyung Lee, Jae Kyoung Lee, Yoon Jin Kim, Joo Hwan Yoo, Dr. Jung Nam Im (Korea Institute of Industrial Technology), and Prof. Moo-Sung Lee (Chonnam National University) for their helpful advices. This research was supported by a grant from the Fundamental R&D Program for Core Technology of materials (10037182, Structuring Technologies for Multi- functionally Converged Nanofibers) funded by Ministry of Trade, Industry & Energy, Republic of Korea. This work was also partially supported by the National Research Foundation of Korea grant funded by the Ministry of Science, ICT & Future Planning (Grant 2012R1A2A2A06046931).
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